This work investigates the feasibility of the coupled electrochemical (electrocoagulation/flotation) and physical processes such as sedimentation, sand filtration, and activated carbon for treatment of automotive service wastewater (ASWW). The impacts of critical parameters viz. pH solution (5-9), reaction time (30-90) and current intensity (1-2) on linear alkylbenzene sulphonate (LAS) and phenol removal efficiencies as well as energy consumption and operating cost are studied. Central composite design (CCD) as a response surface methodology (RSM) is employed. The results reveal by increasing current intensity at low levels of pH, the phenol removal efficiency was increased significantly up to 95%. On the other hand, at pH 9.5 with current intensity of 1.5A, the highest removal efficiency of LAS was achieved with 98.5%. Moreover, at the optimum conditions, LAS and phenol removal efficiencies, energy consumption and operating cost are obtained 96.7%, 87.65%, 15.99 Wh, 0.001 US$, respectively. This process reveals a feasible technology for phenol and LAS removal from ASWW.