Land-surface characteristics (LSCs) and land-soil moisture conditions can modulate energy partition at the land surface, impact near-surface atmosphere conditions, and further affect land–atmosphere interactions. This study investigates the effect of land-surface-characteristic parameters (LSCPs) including albedo, leaf-area index (LAI), and soil moisture (SM) on hot weather by in East China using the numerical model. Simulations using the Weather Research and Forecasting (WRF) Model were conducted for a hot weather event with a high spatial resolution of 1 km in domain 3 by using ERA-Interim forcing fields on 20 July 2017 until 16:00 UTC on 25 July 2017. The satellite-based albedo and LAI, and assimilation-based soil-moisture data of high temporal–spatial resolution, which are more accurate to match fine weather forecasts and high-resolution simulations, were used to update the default LSCPs. A control simulation with the default LSCPs (WRF_CTL), a main sensitivity simulation with the updated LSCP albedo, LAI and SM (WRF_CHAR), and a series of other sensitivity simulations with one or two updated LSCPs were performed. Results show that WRF_CTL could reproduce the spatial distribution of hot weather, but overestimated air temperature (Ta) and maximal air temperature (Tamax) with a warming bias of 1.05 and 1.32 °C, respectively. However, the WRF_CHAR simulation reduced the warming bias, and improved the simulated Ta and Tamax with reducing relative biases of 33.08% and 29.24%, respectively. Compared to the WRF_CTL, WRF_CHAR presented a negative sensible heat-flux difference, positive latent heat flux, and net radiation difference of the area average. LSCPs modulated the partition of available land-surface energy and then changed the air temperature. On the basis of statistical-correlation analysis, the soil moisture of the top 10 cm is the main factor to improve warming bias on hot weather in East China.