The present study deals with the unsteady Walter’s-B fluid with hybrid fractional derivative namely constant proportional Caputo type with singular kernel. In this paper, we find new analytical solutions of a well-known problem of the fluid dynamics known as Stokes’ first problem. Using dimensional variables governing equations convert into dimensionless form. To solve the model analytically, one uses the Laplace transform approach. Analytical and numerical evaluations of the inverse Laplace transform have been conducted. The influence of several embedded flow properties, including the magnetic parameter, Grashof number, dimensionless time, Prandtl number, Schmidt number, and fractional parameter is analyzed graphically. More specifically, compared to the classical model, the fractional model provides a wider range of integral curves and better represents the flow behavior. The temperature and velocity of the fluid decrease with increasing fractional parameters during short intervals of time, but exhibit the reverse pattern over longer durations. Skin friction, the Sherwood number, and the Nusselt number are numerical quantities linked to engineering that are statistically computed and provided in tabular form.