Impact of metalloporphyrin‐based porous coordination polymers on catalytic activities for the oxidation of alkylbenzene

Lü, Xiang‐fei; Du, Yan xia; Mele, Giuseppe; Li, Jun; Ni, Wei; Zhao, Y

doi:10.1002/aoc.5501

Cited by 7 publications

(1 citation statement)

References 40 publications

(52 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Among the many types of synthetic methods developed over the years, the direct C-H oxygenation method is the most important, as C-H bonds are present in abundance in organic compounds [12][13][14][15][16][17][18]. Earlier, hypervalent metals or peroxides were indispensable in C-H oxygenation reactions [19][20][21][22][23][24][25][26][27][28][29][30]. However, the formation of metal wastes and operational risks restricted the development of this strategy.…”

Section: Introductionmentioning

confidence: 99%

Visible-Light-Induced Formation of Aromatic Ketones: A Metal-Free C−H Oxygenation Process in Air under Room Temperature

Xie¹,

Du²,

Cheng³

et al. 2022

View full text Add to dashboard Cite

The process of light-induced C-H oxygenation is of high interest as it can be used for the construction of oxygenated compounds. Herein, we report a mild and general method for the efficient synthesis of aromatic ketones following the process of metal-free C-H oxygenation. With air as the oxidant, high functional tolerance was demonstrated, and the desired ketones were obtained in moderate to excellent yields at room temperature (25 oC). Mechanistic studies suggested that the oxidative transformation potentially occurred via an electron transfer pathway.

show abstract

Section: Introductionmentioning

confidence: 99%

Visible-Light-Induced Formation of Aromatic Ketones: A Metal-Free C−H Oxygenation Process in Air under Room Temperature

Xie¹,

Du²,

Cheng³

et al. 2022

View full text Add to dashboard Cite

show abstract

Recent Development of Porous Porphyrin‐based Nanomaterials for Photocatalysis

Lin

Miao

et al. 2020

ChemCatChem

View full text Add to dashboard Cite

Porphyrins and their derivatives are abundant in nature and play an important role in plant photosynthesis. To mimic the photosynthetic reactions in plants, researchers have developed numerous porphyrin‐based nanomaterials to convert light into chemical energy. And the porous porphyrin‐based nanomaterials attract great interest in photocatalysis owing to their high surface areas, designable structure, and favorable photocatalytic behavior. In this review, we highlight the recent progress of porous porphyrin‐based nanomaterials for photocatalysis. We offer a structured description of the main classes of the porous porphyrin‐based nanomaterials which consist of metal‐organic frameworks (MOFs), covalent‐organic frameworks (COFs), amorphous porous organic polymers (APOPs), and hydrogen bonding‐organic frameworks (HOFs). Strategies to improve their photocatalytic behavior in respect of how to boost the photoexcited electron‐hole separation and increase the accessible active sites are mainly highlighted. At last, the prospects and challenges of porous porphyrin‐based nanomaterials for photocatalysis are also discussed.

show abstract