The surface preparation for depositing Al 2 O 3 for fabricating Au/Ni/Al 2 O 3 /n-GaN (0001) metal oxide semiconductor (MOS) capacitors was optimized as a step toward realization of high performance GaN MOSFETs. The GaN surface treatments studied included cleaning with piranha (H 2 O 2 :H 2 SO 4 ¼ 1:5), (NH 4 ) 2 S, and 30% HF etches. By several metrics, the MOS capacitor with the piranha-etched GaN had the best characteristics. It had the lowest capacitance-voltage hysteresis, the smoothest Al 2 O 3 surface as determined by atomic force microscopy (0.2 nm surface roughness), the lowest carbon concentration ($0.78%) at the Al 2 O 3 /n-GaN interface (from x-ray photoelectron spectroscopy), and the lowest oxide-trap charge (Q T ¼ 1.6 Â 10 11 cm À2 eV À1