Impact of the proximity effect on uranyl coordination of conformationally variable weakly-bonded cucurbit[6]uril-bipyridinium pseudorotaxane

Abstract

To explore the proximity effect in uranyl coordination of weak-bonded cucurbit[6]uril(CB[6])-bipyridinium ligands, a new pseudorotaxane precursor C7BPCN3@CB[6] containing 1, 1'-(heptyl-1,7-diyl)bis(3-cyanopyridin-1-ium) bromide (C7BPCN3) with elongated alkyl chains and meta-substituted cyano groups,...