Travertine deposits are formed after CO2 is
degassed
from deep karst water at the Huanglong Scenic Area, a World Natural
Heritage Site. In recent years, various levels of eutrophication have
occurred in travertine waters, resulting in large areas of algal mats
that have severely affected the continued deposition of travertine
and its appreciable value. The research on hydrochemical types, hydrochemical
components, and pollution characteristics of surface water and groundwater
in Huanglong National Scenic Area, a World Natural Heritage, is beneficial
to the evaluation and management of regional water resources and landscape
development. In June 2022, 14 groups of surface water and groundwater
samples were collected from Huanglong. Mathematical statistics were
used to analyze the water’s chemical characteristics, the Piper
three-plot was used to analyze the water’s chemical types,
and Gibbs and Gaillardet model were used to discuss the sources and
influencing factors of main ions in surface water. The eutrophication
degree of regional water was evaluated by the single factor index
method. The results show that most of the groundwater in the study
area belongs to weakly alkaline water. The cations are mainly Ca2+, the anions are mainly HCO3
–, and the hydrochemical type is HCO3–Ca. The major
contribution of TDS comes from Ca2+ and HCO3
–. According to the analysis of water–rock
model, the hydrochemical origin of surface water in the study area
is mainly controlled by rock weathering, and most ions are influenced
by the water–rock interaction of carbonate rocks, with the
existence of reverse cation exchange. The spatial and temporal distribution
characteristics of nitrogen, phosphorus, and carbon are obvious. Eutrophication
evaluation showed that Huanglong was in a medium eutrophication state.