2010
DOI: 10.1002/crat.201000287
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Impedance analysis and high temperature conduction mechanism of flux grown Pb(Zn1/3Nb2/3)0.91Ti0.09O3 single crystal

Abstract: The electrical properties of Pb(Zn1/3 Nb2/3)0.91Ti0.09O3 single crystals over a wide range of frequencies (20 Hz to 2 MHz) and temperature (30 to 490 °C) were studied using impedance spectroscopic technique. A strongly frequency dependant Debye type relaxation process in crystals was observed. The activation energy for relaxation was found to be 1.72 eV. The nature of Cole‐Cole plot reveals the contribution of only grain (bulk) effect in the sample. The temperature dependant conductivity was found to different… Show more

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Cited by 46 publications
(21 citation statements)
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“…We obtained a gradual decrease in this activation energy from 360 to 213meV when increasing frequency from 100Hz to 1MHz, respectively. A similar kind of behavior has also been reported in the literature [13,15]. Such a decrease can be attributed to the fact that the increase of the applied field enhances the charge carrier's jumps between the localized states [16].…”
Section: Methodssupporting
confidence: 64%
“…We obtained a gradual decrease in this activation energy from 360 to 213meV when increasing frequency from 100Hz to 1MHz, respectively. A similar kind of behavior has also been reported in the literature [13,15]. Such a decrease can be attributed to the fact that the increase of the applied field enhances the charge carrier's jumps between the localized states [16].…”
Section: Methodssupporting
confidence: 64%
“…The values of activation energy are ranging between 0.6 eV and 1.14 eV for the compositions x = 0, 0.05 and 0.10, which is coherent with doubly ionized oxygen vacancies. However, the higher activation energy found for both Rg and Rgb (1.6 eV) in the composition (x = 0.02) can be attributed to the conduction process associate with barium vacancies [42].…”
Section: Impedance Spectroscopymentioning
confidence: 85%
“…At low frequency, it decreases with the increase of temperature; at high frequency, it decreases at first and then becomes stable with increasing temperature. A depression of the M modulus with temperature at high frequency is observed, which could be attribute to the conduction mechanism that is due to the short range mobility of charge carriers . From Fig.…”
Section: Resultsmentioning
confidence: 99%