Three-dimensional pore network reconstructions of mudstone properties are made using dual focused ion beam-scanning electron microscopy (FIB-SEM). Samples of Jurassic Haynesville Formation mudstone are examined with FIB-SEM and image analysis to determine pore properties, topology, and tortuosity. Resolvable pore morphologies (>~10 nm) include large slit-like pores between clay aggregates and smaller pores in strain shadows surrounding larger clastic grains. Mercury injection capillary pressure (MICP) data suggest a dominant 1-10 nm or less size of pores barely resolvable by FIB-SEM imaging. Computational fluid dynamics modelling is used to calculate single phase permeability of the larger pore networks on the order of a few nanodarcys (which compare favourably with core-scale permeability tests). This suggests a pore hierarchy wherein permeability may be limited by connected networks of inter-aggregate pores larger than about 20 nm, while MICP results reflect smaller connected networks of pores residing in the clay matrix. [Received: May 12, 2011; Accepted: September 14, 2011] Keywords: shale gas; Haynesville formation; pore networks; focused ion beam; FIB.Reference to this paper should be made as follows: Dewers, T.A., Heath, J., Ewy, R. and Duranti, L. (2012) 'Three-dimensional pore networks and transport properties of a shale gas formation determined from focused ion beam serial imaging ', Int. J. Oil, Gas and Coal Technology, Vol. 5, Nos. 2/3,
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T.A. Dewers et al.Biographical notes: Thomas A. Dewers is a principal member of the technical staff in the Geomechanics Department at Sandia National Laboratories in Albuquerque, New Mexico. He has over 21 years experience in industry, academia, and government relating to work in the geosciences, and holds a PhD in Geology. His current research interests include nano-to-reservoir scale inquiries into rock mechanics, multiphase flow and reactive transport.Jason Heath is a senior member of the technical staff of the Geophysics and Atmospheric Sciences Department, Sandia National Laboratories, Albuquerque, New Mexico. He has a PhD and MS in Hydrology and Geology, respectively. His research focuses on efficiently estimating well injectivity for large-scale CO 2 storage projects, CO 2 -water-rock interactions, and caprock sealing behaviour.