The paper addresses the issue of modelling the demand for electricity in residential buildings with the use of artificial neural networks (ANNs). Real data for six houses in Switzerland fitted with measurement meters was used in the research. Their original frequency of 1 Hz (one-second readings) was re-sampled to a frequency of 1/600 Hz, which corresponds to a period of ten minutes. Out-of-sample forecasts verified the ability of ANNs to disaggregate electricity usage for specific applications (electricity receivers). Four categories of electricity consumption were distinguished: (i) fridge, (ii) washing machine, (iii) personal computer, and (iv) freezer. Both standard ANNs with multilayer perceptron architecture and newer types of networks based on deep learning were used. The simulations included over 10,000 ANNs with different architecture (number of neurons and structure of their connections), type and number of input variables, formulas of activation functions, training algorithms, and other parameters. The research confirmed the possibility of using ANNs to model the disaggregation of electricity consumption based on low frequency data, and suggested ways to build highly optimised models.