Implementing the Ambiphilicity of an Organotellurenyl Cation for the Synthesis of a Platinum(II)‐Based Carboxylate‐Bridged Heterobimetallic Complex: Structure and Bonding Analysis
Abstract:The metathesis reaction of aryltellurium chloride, ppyTeCl [ppy = 2-(2'-pyridyl)phenyl] (5) with AgClO 4 afforded Intramolecular Chalcogen Bonding (IChB)-stabilized organotellurenyl cation [ppyTe] • ClO 4 ([6] • ClO 4 ). The reaction of [6] • ClO 4 with K 2 PtCl 4 in acetic acid resulted in the formation of platinum(II)-based carboxylate-bridged heterobimetallic complex [Pt(ppyTe)(μ-OOCMe)Cl 2 ], 7 containing an organotellurenyl cation as ligand. This is the first time a Pt(II) complex of an organotellurenyl … Show more
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