We calculate the branching ratios for B 0 d → (b 1 , h 1 ) γ at next-to-leading order (NLO) of α s where b 1 and h 1 are the corresponding radially excited axial vector mesons of ρ and ω respectively. Using the SU (3) symmetry for the form factor, the branching ratio for B 0 d → (b 1 , h 1 ) γ is expressed in terms of the branching ratio of the B 0 d → K 1 γ and it is found to be. We also calculate direct CP asymmetry for these decays and find, in confirmity with the observations made in the literature, that the hard spectator contributions significantely reduces the asymmetry arising from the vertex corrections alone. The value of CP-asymmetry is 10% and is negative like ρ and ω in the Standard Model.1 E-mail: jamil@ncp.edu.pk 2 E-mail: riazuddin@ncp.edu.pk 1 1. Introduction. The Flavor-Changing-Neutral-Current (FCNC) processes which cause b → sγ and b → dγ decays may contain new physics (NP) effects through penguin amplitudes. As the SM effects represent the back ground when we search for NP effects, we shall compute these effects. In doing so, we can understand the sensitivity of each NP search.The first experimental evidence of this FCNC transition process in B decay was observed about a decade ago, where the inclusive process b → sγ and exclusive process B → K * γ were detected, and their branching ratios were measured [1,2]. On the other hand, the expected branching ratio for b → dγ is suppressed by O 10 −2 with respect to the b → sγ, because of the Cabbibo-Kobayashi-Masukawa quark mixing matrix factor (CKM). The world average for b → d penguin decays are given as follow [3]