“…[8][9][10] Among the POMs, the area of polyoxovanadate (POV)-based materials has received special attention, which is due not only to their diverse topologies, 11,12 structural 13 and electronic properties 14 but also to their fascinating versatile industrial applications, e.g., in catalysis, 15 materials, 16,17 and biomedicine. 18,19 Their biological activity derives mainly from their redox behaviour, their biomimetic activity, or from their capability to interact with biological macromolecules through electrostatic interactions. 20 Vanadium(IV)-and vanadium(V)based compounds have been tested for their potential biomedical use in the treatment of diabetes mellitus, cancer, bacterial diseases and viral infections.…”