Incorporation of main group elements into the π-conjugated frameworks is a sophisticated strategy to alter the fundamental nature of the parent conjugated πsystems, giving rise to attractive electronic and photophysical properties that are otherwise inaccessible with classic carbon-or metal-based materials. Out of all πconjugated heterocycles, those that are structurally constrained by tethered aryl substituents surrounding the main group center deserve a great deal of attention because not only do they commonly possess the maximum efficiency of π-conjugation and intermolecular interaction, but they also enjoy remarkable thermal and morphological stabilities that are especially crucial for solid-state performances. In certain cases, elucidation of the behavior of such compounds may additionally provide sufficient perspective toward graphene materials doped with main group elements, which are widely considered as potential next-generation optoelectronic materials. In this review, we will specifically focus on historical developments of structurally constrained polycyclic π-electron systems particularly of those with boron, nitrogen, silicon, or phosphorus atoms annulated directly into the center of π-conjugated systems.
CONTENTSReview pubs.acs.org/CR