Studying the temperature field of photovoltaic modules is important for improving their power generation efficiency. To solve the problem of traditional sensors being unsuitable for measuring the spatial temperature field, we designed a real-time detection scheme of the photovoltaic module temperature field based on a fiber Bragg grating (FBG) sensor array. In this scheme, wavelength division multiplexing and space division multiplexing technologies were applied. The multi-channel FBG sensor strings were arranged on the surface and in the near field of the photovoltaic module. Different FBG strings were selected through optical switches, and the wavelength of the FBG string was addressed and demodulated using the tunable laser method and a peak-seeking algorithm. A measurement experiment of the photovoltaic module temperature field was carried out in an outdoor environment. The experimental results showed that the fluctuation law of the photovoltaic module surface and near-field temperature is basically consistent with that of solar radiation power. The temperature of the photovoltaic module decayed from the surface to space. Within 6 mm of the photovoltaic module surface, the temperature sharply dropped, and then the downward trend became flat. The lower the solar radiation power and the higher the wind speed, the faster the temperature decay. This method provides technical support for measuring the temperature field of a photovoltaic module and other heat source equipment.