Aggregates of niobium–alumina refractory composites are characterized, which are produced by a castable technology followed by a crushing process. Phase separation between niobium and corundum is found for the obtained aggregate classes and the impurity phases NbO and β–Nb2C are present according to X‐ray diffraction measurements. Among the studied aggregate classes, niobium shows differences in chemistry expressed by the corresponding lattice parameters. The determined morphology and roughness parameters show that the synthesized aggregates are not substantial different independent of their density and porosity.