In recent years, a series of serious attacks against industrial control system (ICS), such as Stuxnet, Duqu, Flame and Havex, have sounded the alarm for industrial enterprises. For many industrial enterprises, it is a very important part of enterprise management decisions to evaluate ICS security suppliers and choose the appropriate one as a partner. The purpose of this paper is to build the TODIM method based on cumulative prospect theory (CPT-TODIM) to solve multiattribute group decision making problem under interval-valued bipolar fuzzy environment. This extraordinary model not only uses CPT to supplement the traditional TODIM method, but also introduces the entropy weight method to determine the attribute weight so as to avoid the negative influence of subjective weight on the decision result. In addition, in this model, all attribute evaluation information will be interval-valued bipolar fuzzy number (IVBFN) to cope with complex and fuzzy decision environment. Then, the most important part of this paper, we elaborate on the logical structure of the model. What’s more, in the last two sections, we apply this newly constructed model to the selection of ICS security suppliers, and verify the acceptability of this method by sensitivity analysis and comparing with IVBFWA and IVBFWG operator.