Improvement of charge/discharge performance for lithium ion batteries with tungsten trioxide electrodes

Li, Wei; Sasaki, Takehiko; Oozu, Hideyuki; Aoki, Katsuaki; Kakushima, Kuniyuki; Kataoka, Yuki; Nishiyama, Akira; Sugii, Nobuyuki; Wakabayashi, Hitoshi; Tsutsui, Kazuo; Natori, Kenji

doi:10.1016/j.microrel.2014.11.002

Cited by 21 publications

(12 citation statements)

References 20 publications

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“…9a). The capacity values reached are however equal to WO 3 in bulk (powder) form using a comparable voltage range, 20 indicating that at least in case of TiN as substrate sufficient crystallinity and phase stability is reached.…”

Section: Electrochemical Analysismentioning

confidence: 87%

See 1 more Smart Citation

From liquid to thin film: colloidal suspensions for tungsten oxide as an electrode material for Li-ion batteries

Ham

Elen

Kokal³

et al. 2016

RSC Adv.

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Section: Electrochemical Analysismentioning

confidence: 87%

“…[13][14][15][16][17][18][19] Although various reports indicate the superiority of LTO as an oxide based negative electrode according to its higher energy density, the WO 3 outclasses the LTO according to its volumetric capacity 604 (ref. 20) vs. 228 mA h cm À3 (ref. 21 and 22).…”

Section: Introductionmentioning

confidence: 99%

From liquid to thin film: colloidal suspensions for tungsten oxide as an electrode material for Li-ion batteries

Ham

Elen

Kokal³

et al. 2016

RSC Adv.

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“…Heat treatment is the most important way to introduce OVs in a crystal architecture. Li et al fabricated crystalline WO 3 with OVs by a facile calcination treatment at ambient N 2 . As anode of LIBs, the WO 3 with OVs can evidently improve the conductivity of work electrodes and Li + transportation.…”

Section: Tungsten‐based Materials For Libsmentioning

confidence: 99%

Tungsten‐Based Materials for Lithium‐Ion Batteries

Zheng

Tang

et al. 2018

Adv Funct Materials

136

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Lithium-ion batteries are widely used as reliable electrochemical energy storage devices due to their high energy density and excellent cycling performance. The search for anode materials with excellent electrochemical performances remains critical to the further development of lithium-ion batteries. Tungsten-based materials are receiving considerable attention as promising anode materials for lithium-ion batteries owing to their high intrinsic density and rich framework diversity. This review describes the advances of exploratory research on tungsten-based materials (tungsten oxide, tungsten sulfide, tungsten diselenide, and their composites) in lithium-ion batteries, including synthesis methods, microstructures, and electrochemical performance. Some personal prospects for the further development of this field are also proposed.

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“…Though the gravimetric capacity of this electrode material is mediocre, the volumetric energy density is higher than most other oxide electrode materials. For instance, the volumetric density of WO 3 is 604 mAh·cm −3 [ 33 , 34 ], whereas the Li 4 Ti 5 O 12 (LTO) has a capacity of only 228 mAh·cm −3 [ 5 ]. For all-solid-state batteries the latter is arguably the most important device parameter.…”

Section: Introductionmentioning

confidence: 99%

Wet-Chemical Synthesis of 3D Stacked Thin Film Metal-Oxides for All-Solid-State Li-Ion Batteries

et al. 2017

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By ultrasonic spray deposition of precursors, conformal deposition on 3D surfaces of tungsten oxide (WO 3 ) negative electrode and amorphous lithium lanthanum titanium oxide (LLT) solid-electrolyte has been achieved as well as an all-solid-state half-cell. Electrochemical activity was achieved of the WO 3 layers, annealed at temperatures of 500 • C. Galvanostatic measurements show a volumetric capacity (415 mAh·cm −3 ) of the deposited electrode material. In addition, electrochemical activity was shown for half-cells, created by coating WO 3 with LLT as the solid-state electrolyte. The electron blocking properties of the LLT solid-electrolyte was shown by ferrocene reduction. 3D depositions were done on various micro-sized Si template structures, showing fully covering coatings of both WO 3 and LLT. Finally, the thermal budget required for WO 3 layer deposition was minimized, which enabled attaining active WO 3 on 3D TiN/Si micro-cylinders. A 2.6-fold capacity increase for the 3D-structured WO 3 was shown, with the same current density per coated area.

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Improvement of charge/discharge performance for lithium ion batteries with tungsten trioxide electrodes

Cited by 21 publications

References 20 publications

From liquid to thin film: colloidal suspensions for tungsten oxide as an electrode material for Li-ion batteries

From liquid to thin film: colloidal suspensions for tungsten oxide as an electrode material for Li-ion batteries

Tungsten‐Based Materials for Lithium‐Ion Batteries

Wet-Chemical Synthesis of 3D Stacked Thin Film Metal-Oxides for All-Solid-State Li-Ion Batteries

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