Improvement of steam reforming of toluene by CO2 capture using Fe/CaO–Ca12Al14O33 bi-functional materials

Pyrolysis behavior and kinetic study of phenol as tar model compound in micro fluidized bed reactor

“…As a typical byproduct, tar will be condensed when the temperature is lower than its dew point, rendering the blockage of downstream equipments such as engines, filters and turbines [4], which will severely affect the stable operation of equipments [5]. Besides, the generation of tar causes a partial loss of input energy [6,7]. Tar removal has been a key issue for utilizing biomass.…”

Performance and operating limits of a sorbent-catalyst system for sorption-enhanced reforming (SER) in a fluidized bed reactor

“…This inert frame was revealed to be a suitably stable support for CaO-based sorbent materials operating in the temperature range of interest for the process (i.e. 600-925 ºC) (Kazi et al, 2014;Li et al, 2006a;Mastin et al, 2011;Zamboni et al, 2015). The CaO-Ca12Al14O33 sorbent powder contained 30 wt% CaO and 70 wt% Ca12Al14O33, and it was prepared according to the hydrothermal synthesis route reported by Kazi et al (2014) using calcium hydroxide (Ca(OH)2, Balthazard & Cotte) and aluminium hydroxide (Al(OH)3, Alumines Durmax SG27) as precursors.…”

Catalytic steam methane reforming enhanced by CO2 capture on CaO based bi-functional compounds

“…The impregnation was performed on high temperature Cabased solid sorbents previously synthesized by wet mixing synthesis. This latter consisted in a dissolution of calcium oxide and aluminum nitrate nonahydrate in an aqueous solution, following by a heating and two calcination steps [17,18] . The slurry of Cabased solid sorbent and aqueous solution of nickel nitrate is dried at 120 °C during 12 h [19] or 36 h when mayenite amount exceeds 70 wt% in the synthesized samples.…”