Improvement strategies on application of covalent organic frameworks in adsorption, photocatalytic, and membrane processes for organic pollution removal from water

Asayesh-Ardakani, Elham; Rahmani, Maryam; Hosseinian, Akram; Ghaffari, Seyed-Behnam; Sarrafzadeh, Mohammad-Hossein

doi:10.1016/j.ccr.2024.216087

Coordination Chemistry Reviews

2024

DOI: 10.1016/j.ccr.2024.216087

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Improvement strategies on application of covalent organic frameworks in adsorption, photocatalytic, and membrane processes for organic pollution removal from water

Elham Asayesh-Ardakani,

Maryam Rahmani,

Akram Hosseinian

et al.

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Cited by 5 publications

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Covalent organic frameworks: a review of synthesis methods, properties and applications for per- and poly-fluoroalkyl substances removal

Issaka,

Adams,

Baffoe

et al. 2024

Clean Techn Environ Policy

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Adsorption using covalent organic frameworks (COFs) is very effective and favoured for removing per- and polyfluoroalkyl substances (PFAS) from various matrices. The prominent classes of COF, their synthesis methods, and their application in COF-based technologies for PFAS adsorption in myriad environments are discussed. Furthermore, the influencing PFAS adsorption characteristics of the distinct COF classes are also examined. COFs have large specific surface areas and porosity, offering PFASs a host of adsorption sites and thus high adsorption capabilities. β-Cyclodextrin-based COFs (β-CD-COFs), ionic COFs (iCOFs), amine-functionalised COFs, porphyrin-based COFs and hydrophobic COFs are some of the most notable examples of COFs and as such have been employed for large-scale PFAS remediation. Direct and post-synthetic modification are the two main COF design methodologies. The general approach in constructing various frameworks involves the reaction of ion monomers with other neutral monomers. For COFs, solvothermal synthesis is currently the main direct synthetic method. The process used to synthesise COFs tremendously impacts how effectively they adsorb PFAS. High-performance materials for PFAS remediation are created by researchers by customising COF characteristics and using suitable synthesis techniques. The authors’ objective is to give readers and researchers alike a broad overview of the current status of COF research and development, including numerous challenges and prospects associated with the adsorption of PFASs by COFs. Graphical abstract Application of Cement Stabilized OB dump, BOF slag, Fly Ash Mixes as Sustainable Pavement Material

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Covalent organic frameworks: a review of synthesis methods, properties and applications for per- and poly-fluoroalkyl substances removal

Issaka,

Adams,

Baffoe

et al. 2024

Clean Techn Environ Policy

View full text Add to dashboard Cite

show abstract

Fe-doped MOF(Ti)/Bi2MoO6 heterostructure for boosting oxidation/reduction activities under visible light

Luo,

Liao,

Peng

et al. 2025

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Molecularly imprinted polymers @ metal and covalent organic frameworks: From synthesis to application in analytical chemistry

Nomngongo,

Selahle,

Mpupa

et al. 2024

TrAC Trends in Analytical Chemistry

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Improvement strategies on application of covalent organic frameworks in adsorption, photocatalytic, and membrane processes for organic pollution removal from water

Cited by 5 publications

References 256 publications

Covalent organic frameworks: a review of synthesis methods, properties and applications for per- and poly-fluoroalkyl substances removal

Covalent organic frameworks: a review of synthesis methods, properties and applications for per- and poly-fluoroalkyl substances removal

Fe-doped MOF(Ti)/Bi2MoO6 heterostructure for boosting oxidation/reduction activities under visible light

Molecularly imprinted polymers @ metal and covalent organic frameworks: From synthesis to application in analytical chemistry

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