Improvements in Methyl Ethyl Ketone Production Through Intensified Processes

Sánchez‐Ramírez, Eduardo; Alcocer‐García, Heriberto; Romero-García, Ana Gabriela; Contreras-Zarazúa, Gabriel; Segovia‐Hernández, Juan Gabriel

doi:10.1016/b978-0-323-88506-5.50063-2

Cited by 2 publications

(1 citation statement)

References 11 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…As a matter of fact, the remaining C4 mixture after the separation of 1-butene is rich in 2-butene, including cis -2-butene and trans -2-butene, which can be just used as a fuel. However, 2-butene can be utilized together with 1-butene to produce methyl ethyl ketone (MEK) via the hydration of 1-butene/2-butene 7 or isobutene via the skeletal isomerization of the linear butene 8 or propylene via butene cross-metathesis. 9 Recently, the conversion of 2-butene into 1-butene via double bond isomerization has also been paid much attention in both academia and industry.…”

Section: Introductionmentioning

confidence: 99%

UiO-66 derived ZrO₂@C catalysts for the double-bond isomerization reaction of 2-butene

et al. 2023

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

UiO-66 derived ZrO₂@C catalysts for the double-bond isomerization reaction of 2-butene

et al. 2023

View full text Add to dashboard Cite

show abstract

Synthesis of highly basic, low-cost iron oxides from tin can waste as valorization of municipal solid waste and study of their catalytic efficiency as potent catalysts for MEK production

Gomaa,

Osman,

Halawy

et al. 2023

J Mater Cycles Waste Manag

View full text Add to dashboard Cite

In the present study, low-cost iron oxide catalysts have been prepared by a simple precipitation method using tin food can waste as a source of iron and sodium hydroxide or ammonium hydroxide solution as a precipitating agent. The prepared catalysts were characterized by thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), FT-IR spectra, scanning electron microscopy (SEM), EDAX quantitative elemental analysis, and BET surface area measurements. Surface basicity of iron oxide catalysts was measured by adsorption of carbon dioxide as an acidic probe molecule, followed by desorption measurements using the TGA technique. The prepared iron oxide catalysts were tested by dehydrogenation of 2-butanol to methyl ethyl ketone (MEK) at a temperature range of 275–375 °C. Commercial iron oxide was tested under identical reaction conditions for comparison with the prepared catalysts. The results indicated the superiority of the prepared catalysts over the commercial one and the superiority of the catalyst prepared using NaOH over that prepared using NH4OH as precipitating agents. The use of different precipitating agents affects the surface morphology and, consequently, the catalytic activity of the produced iron oxide catalysts. Graphical abstract

show abstract

Improvements in Methyl Ethyl Ketone Production Through Intensified Processes

Cited by 2 publications

References 11 publications

UiO-66 derived ZrO₂@C catalysts for the double-bond isomerization reaction of 2-butene

UiO-66 derived ZrO₂@C catalysts for the double-bond isomerization reaction of 2-butene

Synthesis of highly basic, low-cost iron oxides from tin can waste as valorization of municipal solid waste and study of their catalytic efficiency as potent catalysts for MEK production

Contact Info

Product

Resources

About

Improvements in Methyl Ethyl Ketone Production Through Intensified Processes

Cited by 2 publications

References 11 publications

UiO-66 derived ZrO2@C catalysts for the double-bond isomerization reaction of 2-butene

UiO-66 derived ZrO2@C catalysts for the double-bond isomerization reaction of 2-butene

Synthesis of highly basic, low-cost iron oxides from tin can waste as valorization of municipal solid waste and study of their catalytic efficiency as potent catalysts for MEK production

Contact Info

Product

Resources

About

UiO-66 derived ZrO₂@C catalysts for the double-bond isomerization reaction of 2-butene

UiO-66 derived ZrO₂@C catalysts for the double-bond isomerization reaction of 2-butene