The transition to sustainable mobility is a recognized socio-economic and environmental challenge, particularly among young adults. In addressing the gap in the literature on young adults’ travel behaviors, especially in Cameroon, this paper investigates the transport mode choices, influencing factors, and barriers to sustainable mobility of students at the National Advanced School of Public Works, Yaoundé (NASPW). Data were collected through online questionnaires with 360 valid responses. Findings revealed that most students used multiple modes of transport for commuting, with moto-taxis being the most common. Accessibility, vehicle speed, and flexibility appeared as the most important reasons for the preferred transport modes, while driver’s license possession, safety perceptions, speed, and proximity were significant predictors for mode choice. Demographic factors were found to influence transport preferences, with distinct clusters prioritizing different aspects. Barriers to public transport were primarily long waiting times and congestion, while active mobility was hindered by distance, infrastructure, and weather. The usage of public transportation was encouraged by its affordability and reduced travel time, whilst active options were preferred due to cost savings and health benefits. To promote sustainable mobility for campus travel, it is crucial to encourage active modes, develop mass transport systems, and raise awareness through symposia and conferences among students and staff.