We develop an approach to spectral estimation that has been advocated by Ferrante, Masiero and Pavon [2] and, in the context of the scalar-valued covariance extension problem, by Enqvist and Karlsson [3]. The aim is to determine the power spectrum that is consistent with given moments and minimizes the relative entropy between the probability law of the underlying Gaussian stochastic process to that of a prior. The approach is analogous to the framework of earlier work by Byrnes, Georgiou and Lindquist and can also be viewed as a generalization of the classical work by Burg and Jaynes on the maximum entropy method.In the present paper we present a new fast algorithm in the general case (i.e., for general Gaussian priors) and show that for priors with a specific structure the solution can be given in closed form. 1 [36, Chapter 4.5]; see [43], [44], [45] for multivariable generalizations. 2 [36, Chapter 5.4]; see [46] for points of contact to the problem of moments.