We have observed an unusual transition which is predicted to result in visible and near-uv emission from very highly charged titaniumlike ions spanning the entire upper half of the periodic table. Measurements of the wavelengths of the 3d 'D2-D3 transitions in Ba+ and Xe+ are in surprisingly poor agreement with ab initio calculations. This work was carried out in an electron beam ion trap and demonstrates that such a device can be an important tool for visible spectroscopy of highly charged ions. PACS numbers: 32.70.n, 31.25.v, 52.25.b, 52.70.KzAlthough ions having identical numbers of electrons display similar spectral structure, the scale of many atomic properties changes dramatically as the nuclear charge (Z) is increased along an isoelectronic sequence. One example is the rapid decrease in transition wavelengths leading to the characteristic emission of light in the x-ray region of the spectrum for very highly charged ions. It was therefore unusual when Feldman, Indelicato, and Sugar [1] reported calculations predicting a small set of observable visible and near-uv magnetic dipole (Ml) lines for highly charged ions in the titaniumlike isoelectronic sequence. The upper levels of these transitions lie within the ground term, and, therefore, in low density plasmas (~10'3 cm '), where competition from electron