With the intensification of global warming, droughts and heatwaves occur frequently and widely, which have a serious impact on the healthy growth of vegetation. The challenge is to accurately characterize vegetation vulnerability under compound heat and drought stress using correlation-based methods. This article uses the Haihe River Basin, an ecologically sensitive area known for experiencing droughts nine out of ten years, as an example. Firstly, using daily precipitation and maximum temperature data from 38 meteorological stations in the basin from 1965 to 2019, methods such as univariate linear regression and the Mann–Kendall mutation test were employed to identify the temporal variation patterns of meteorological elements in the basin. Secondly, the Pearson correlation coefficient and other methods were applied to determine the most likely months for compound dry and hot events, and the joint distribution pattern and recurrence period of concurrent high temperature and intense drought events were explored. Finally, a vegetation vulnerability assessment model based on Vine Copula in compound dry and hot climates was constructed to quantify the relationship of the response of watershed vegetation to different extreme events (high temperature, drought, and compound dry and hot climates). The results indicated that the basin’s precipitation keeps decreasing, evaporation rises, and the supply–demand conflict grows more severe. The correlation between the Standardized Precipitation Index (SPI) and Standardized Temperature Index (STI) is strongest at the 3-month scale from June to August. Meanwhile, in most areas of the basin, the Standardized Normalized Difference Vegetation Index (sNDVI) is positively correlated with the SPI and negatively correlated with the STI. Compared to a single drought or high-temperature event, compound dry and hot climates further exacerbate the vegetation vulnerability of the Haihe River Basin. In compound dry and hot climates, the probability of vegetation loss in June, July, and August is as high as 0.45, 0.32, and 0.38, respectively. Moreover, vegetation vulnerability in the southern and northwestern mountainous areas of the basin is higher, and the ecological risk is severe. The research results contribute to an understanding of the vegetation’s response to extreme climate events, aiming to address terrestrial ecosystem risk management in response to climate change.