Moisture has a significant influence on the performance and durability of unbound granular (UBG) pavements with thin bituminous surfacings, which form the vast majority of all-weather Australian roads. Techniques for measuring pavement moisture content are therefore important to quantify its influence on structural performance, enable early detection of problem areas, and to assess the condition of flood-affected pavements.Conventional techniques, however, require invasive probes or physical sampling which are impractical for large-scale investigations. Ground Penetrating Radar (GPR) techniques show promise, yet existing methods achieve only qualitative estimates, involve simplifications that limit accuracy or require complicated or laborious data analysis. The aim of this research was to develop a semi-automated approach using multi-offset GPR to quantitatively estimate the moisture content and depth of UBG pavement layers while maintaining data analysis simplicity.The research made use of a new type of 3-dimensional (3D) GPR technology able to continuously collect ground-coupled multi-offset gathers across the road while travelling at up to traffic speeds. To enable development of analysis methods prior to equipment completion, numerical simulations were used to model the expected response for typical pavement configurations. These data were used to test a semi-automated approach using interface tracking and conventional multi-offset geophysical analysis methods.They were also used to develop two novel self-correcting analysis techniques, Interface Matching (IM) and Ray-path Modelling (RM), which use migration and tomographic approaches, respectively.A permittivity characterisation approach, later called modified free-space (MFS), was also adapted for laboratory characterisation of UBG materials. It was used to calibrate petro-physical relations for these materials that enable pavement moisture estimates from the GPR measurements. As the MFS approach departs from conventional freespace methods, numerical modelling and a series of laboratory experiments were used to assess measurement accuracy and to determine the influence of sample edges, aspect ratio, and depth and antenna separation on the measurements. These investigations demonstrated that the MFS approach was suitable using the proposed equipment, sample sizes and for the range of relative permittivity values likely to be encountered. It also produced results that compared well with established apparatus over the frequency range relevant to pavement GPR.iii Measurements using this approach were also compared with conventional time-domain reflectometry (TDR) and common-offset GPR measurements of moisture-varying and density-varying UBG samples. The comparison showed similar results for most samples, although TDR reported lower relative permittivity values for drier and lowerdensity materials.Upon completion of the 3D GPR equipment, a revised analysis approach called Raypath Modelling-Semblance (RM-S) was developed. It was used to analyse multi-off...