“…On the other hand, it also became clear that the first-order methods were generally unable to reproduce the experimental data for optically forbidden transitions, particularly (1s 2 ) 1 S → (1s3d) 1,3 D ( Bartschat and Madison 1988). A striking example is the circular polarization P 3 of light emitted perpendicular to the scattering plane in the transition (1s3d) 1 D → (1s2p) 1 P o , observed in coincidence with the scattered electron after excitation from the ground state by 40 eV incident electrons (see, for example, McLaughlin et al 1994a). Whereas this energy was too high for the standard R-matrix approach, the CCC method was once again able to reproduce the experimental results very well (Fursa and Bray 1995), thereby indicating the importance of accounting for coupled-channel effects to higher excited discrete and even continuum target states, especially in the 'intermediate energy regime' from the ionization threshold to a few times this energy.…”