The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air.Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-101 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue.Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. The report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods.Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue. The flammable gas hazard will continue to exist until the wastes are retrieved fiom the tanks. However, DOE plans to resolve the Flammable Gas Safety Issue on a tank-by-tank basis when the following steps are completed: a) determination of the amount and composition of gas retained in the wastes; b) establishment of an adequate understanding of the mechanisms for gas generation, retention and release; and c) updating the Authorization Basis for the Manage Tank Waste Function.The major emphasis of this report is to put the flammable gas hazard into perspective based on our current understanding of the mechanisms driving generation, retention and release of flammable gas mixtures in high-level waste tanks. It provides an overview of what has been learned and what needs to be learned about the phenomena, how the Unreviewed Safety Question will be closed, and the strategy for closing the flammable gas safety issue itself. Section 1 of this report provides an overview of the understanding and needs of the Flammable Gas Safety Issue and Sections 2-7 provide additional details to the information provided in Section 1.The information in this report represents the status of what is known or being done as of the latter part of 1996. As additional information is obtained fiom the characterization of tanks, analyses of data, and development of models and analysis methods, the information in this report will need to be updated.