In situ growth-optimized synthesize of Al-MOF@RGO anode materials with long-life capacity-enhanced lithium-ion storage

Wang, Kai; Chen, Jiangchun; Hou, Fengxiao; Wang, Han; Zhong, Xia; Song, Yuexian; Zhang, Yangang; Zhang, Zhiwen; Liu, Hantao; Liang, Junfei; Wang, Hua

doi:10.1016/j.cej.2022.140561

Cited by 6 publications

(3 citation statements)

References 43 publications

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“…Recently, a reduced graphene oxide based hybrid, rGO@Al-MOF [Al-(OH)[O 2 C−C 6 H 4 −CO 2 ], was used as an anode in LIBs and showed a high specific capacity of 468.5 mAh g −1 (at current density of 1.0 Ag −1 ) after 1000 cycles. 127 In another work, rGO@In-MOF (In-MOF, indium metal ion coordinated with isophthalic acid) was employed as an electrode in a lithium− sulfur (Li−S) battery. 128 It is noteworthy to mention that the reversible capacity of the battery after 100 cycles was found to be 898.7 mAh/g (at 0.2 C) which highlighted the importance of these hybrids for lithium−sulfur batteries.…”

Section: Energy Storagementioning

confidence: 99%

“…In particular, graphene@MOF-based anodes have been designed for lithium-ion batteries (LIBs) to achieve high capacity and excellent cycling stability. Recently, a reduced graphene oxide based hybrid, rGO@Al-MOF [Al(OH)[O 2 C–C 6 H 4 –CO 2 ], was used as an anode in LIBs and showed a high specific capacity of 468.5 mAh g –1 (at current density of 1.0 Ag –1 ) after 1000 cycles . In another work, rGO@In-MOF (In-MOF, indium metal ion coordinated with isophthalic acid) was employed as an electrode in a lithium–sulfur (Li–S) battery .…”

Section: Applicationsmentioning

confidence: 99%

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Hybrid Two-Dimensional Porous Materials

Jayaramulu,

Devi

2023

Chem. Mater.

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Metal–organic frameworks (MOFs) are crystalline materials that consist of metallic clusters and organic ligands with great potential for a diverse range of applications, including but not limited to gas separation and storage, electrocatalysis, water purification, batteries, and supercapacitors. However, their poor conductivity, inaccessible pores, and limited stability hinder their maximum utilization. To overcome these challenges, one solution to this problem is to integrate MOFs with two-dimensional (2D) materials, such as aminoclay, boron nitride, covalent–organic frameworks, graphene derivatives, layered double hydroxides, metal oxides, transition metal dichalcogenides, and transition metal carbides/nitrides, to create emerging multifunctional hybrid two-dimensional porous materials (denoted as H2DPMs) through primary or secondary bonding interactions. These H2DPMs benefit from a rich compositional versatility and tunable properties. Recent efforts have focused on integrating 2D materials with nano MOFs (0D, 1D, 2D, and 3D) to create hybrid materials with enhanced electro- and physicochemical properties, expanding the range of potential applications. H2DPMs have the potential to extract the best of both materials and could be a lucrative option for developing advanced materials. In this Perspective, we discuss the synthesis strategies, properties, challenges, and potential applications of H2DPMs materials. We also discuss the challenges and future directions for hybridizing of MOFs with 2D materials.

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Section: Energy Storagementioning

confidence: 99%

Section: Applicationsmentioning

confidence: 99%

Hybrid Two-Dimensional Porous Materials

Jayaramulu,

Devi

2023

Chem. Mater.

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“…MOFs, composed of metallic centers connected to organic ligands, have garnered growing attention as LIB electrodes. This heightened interest stems from their facile pore structure tuning, substantial specic surface area, and the potential for numerous sites facilitating Li + insertion, thereby resulting in elevated theoretical capacities, [19][20][21][22] as recent reviews report. [23][24][25] The high porosity of MOFs offers the advantage of accommodating the signicant volume expansion arising from conversion reactions, thereby improving the cyclability of the electrodes compared to TMN materials.…”

Section: Introductionmentioning

confidence: 99%

Electrochemical performance of M(dca)₂pyz (M = Fe, Co and Ni) MOFs as sustainable anodes in lithium-ion batteries

Ciria-Ramos,

García-Fernández,

Mayoral

et al. 2024

J. Mater. Chem. A

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High‐Entropy Metal–Organic Frameworks and Their Derivatives: Advances in Design, Synthesis, and Applications for Catalysis and Energy Storage

Xing,

Liu,

Mathew

et al. 2024

Advanced Science

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As a nascent class of high‐entropy materials (HEMs), high‐entropy metal–organic frameworks (HE‐MOFs) have garnered significant attention in the fields of catalysis and renewable energy technology owing to their intriguing features, including abundant active sites, stable framework structure, and adjustable chemical properties. This review offers a comprehensive summary of the latest developments in HE‐MOFs, focusing on functional design, synthesis strategies, and practical applications. This work begins by presenting the design principles for the synthesis strategies of HE‐MOFs, along with a detailed description of commonly employed methods based on existing reports. Subsequently, an elaborate discussion of recent advancements achieved by HE‐MOFs in diverse catalytic systems and energy storage technologies is provided. Benefiting from the application of the high‐entropy strategy, HE‐MOFs, and their derivatives demonstrate exceptional catalytic activity and impressive electrochemical energy storage performance. Finally, this review identifies the prevailing challenges in current HE‐MOFs research and proposes corresponding solutions to provide valuable guidance for the future design of advanced HE‐MOFs with desired properties.

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In situ growth-optimized synthesize of Al-MOF@RGO anode materials with long-life capacity-enhanced lithium-ion storage

Cited by 6 publications

References 43 publications

Hybrid Two-Dimensional Porous Materials

Hybrid Two-Dimensional Porous Materials

Electrochemical performance of M(dca)₂pyz (M = Fe, Co and Ni) MOFs as sustainable anodes in lithium-ion batteries

High‐Entropy Metal–Organic Frameworks and Their Derivatives: Advances in Design, Synthesis, and Applications for Catalysis and Energy Storage

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In situ growth-optimized synthesize of Al-MOF@RGO anode materials with long-life capacity-enhanced lithium-ion storage

Cited by 6 publications

References 43 publications

Hybrid Two-Dimensional Porous Materials

Hybrid Two-Dimensional Porous Materials

Electrochemical performance of M(dca)2pyz (M = Fe, Co and Ni) MOFs as sustainable anodes in lithium-ion batteries

High‐Entropy Metal–Organic Frameworks and Their Derivatives: Advances in Design, Synthesis, and Applications for Catalysis and Energy Storage

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Electrochemical performance of M(dca)₂pyz (M = Fe, Co and Ni) MOFs as sustainable anodes in lithium-ion batteries