“…Mott–Schottky plots and the CB position of the D1 photocatalyst were generated from the potential vs. NHE (normal hydrogen electrode) data graph. The latter was converted from the potential (in volts ‘V’) vs. Ag/AgCl electrode using the following relation, 28,29 V (NHE) = V (Ag/AgCl) + 0.059pH + 0.197 (here pH = 7)…”
Section: Experimental and Computational Methodsmentioning
confidence: 99%
“…15,16 Photoexcitation can concentrate electrons in the less positive CB component and holes in the part with the more positive VB. 28 The latter is called a Z-scheme photocatalyst. It has improved reduction and oxidation driving forces.…”
“…Mott–Schottky plots and the CB position of the D1 photocatalyst were generated from the potential vs. NHE (normal hydrogen electrode) data graph. The latter was converted from the potential (in volts ‘V’) vs. Ag/AgCl electrode using the following relation, 28,29 V (NHE) = V (Ag/AgCl) + 0.059pH + 0.197 (here pH = 7)…”
Section: Experimental and Computational Methodsmentioning
confidence: 99%
“…15,16 Photoexcitation can concentrate electrons in the less positive CB component and holes in the part with the more positive VB. 28 The latter is called a Z-scheme photocatalyst. It has improved reduction and oxidation driving forces.…”
“…Furthermore, they demonstrated that the H 2 O 2 formed in the reaction could degrade tetracycline (by an in situ Fenton-like reaction) in an aqueous medium. 18 Thus, these authors avoided the problems associated with the separation and storage of H 2 O 2 by coupling the production step with another reaction that utilized it for wastewater treatment.…”
The development of recyclable H2O2-producing photocatalysts with in-situ Fenton-like organic pollutant degradation is currently a topical area of research. This research investigates the visible light photocatalytic formation of H2O2 on...
“…Photocatalysis research demands semiconductor nanostructures with appropriate band structures that ensure charge separation and strong redox driving forces. 4–8…”
Section: Introductionmentioning
confidence: 99%
“…Photocatalysis research demands semiconductor nanostructures with appropriate band structures that ensure charge separation and strong redox driving forces. [4][5][6][7][8] Introducing defects like vacancies or dopants into the parent semiconductor material can increase charge separation and alter the bandgap and adsorption properties. For instance, Hezam et al synthesized oxygen vacancy (OV) enriched ceria (CeO 2 ) with better charge separation and enhanced photocatalytic activity.…”
A narrow bandgap restricts photocatalytic applications of Ag2O nanoparticles, but appropriate doping can favorably modify this aspect. Given this, density functional theory (DFT) calculations were conducted, revealing that substitutional sulfur...
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