In Situ Preparation, Crystal Structure and Fluorescence of [(CH3)2–4,4′-H2bipy][FeCl4]2 (Bipy = Bipyridine)

Hydrothermal reactions of molybdenum(III) oxide with isoquinoline under different pH values lead to two new octamolybdate-based polyoxometalates (POMs), namely, (C 9 H 7 NH) 4 (C 9 H 7 N) 2 [Mo 8 O 26 ] (I) and (C 9 H 7 NH) 4 [(Mo 8 O 26 )(C 9 H 7 N) 2 ]·2(H 2 O) (II), and their structures were determined by single-crystal X-ray diffraction analysis. The two compounds represent the first report of [Mo 8 O 26 ] 4-based POMs associated with isoquinoline ligand. Compound (I) has 3D supramolecular framework based on hydrogen bonds between [β-Mo 8 O 26 ] 4-fragment and protonated isoquinoline (C 9 H 7 NH) + . Compound (II) contains [(γ-Mo 8 O 26 )(C 9 H 7 N) 2 ] 4-units constructed by [γ-Mo 8 O 26 ] 4-units and isoquinoline through Mo-N bonds.

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In situ preparation, structure, fluorescence and theoretical study of a cadmium-bipyridinium compound

Pei

Luo

et al. 2019

Inorganic and Nano-Metal Chemistry

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In Situ Preparation, Crystal Structure and Fluorescence of [(CH₃)_2–4,4′-H₂bipy][FeCl₄]₂ (Bipy = Bipyridine)

Cited by 5 publications

References 22 publications

The preparation of a bismuth-based complex and the influence of double protonation

The preparation of a bismuth-based complex and the influence of double protonation

Syntheses and Characterizations of Two New Octamolybdate-Based Polyoxometalates Decorated by Isoquinoline Ligands

In situ preparation, structure, fluorescence and theoretical study of a cadmium-bipyridinium compound

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