2015
DOI: 10.1007/s10971-015-3738-9
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In situ reduction and stabilization of Ag NPs onto magnetic composites for rapid hydrogenation catalysis

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Cited by 11 publications
(6 citation statements)
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“…The rate constant (k) calculated from the slope of the plot was 0.394 min -1 for AgNPs(1)/ZHL and 0.875 min -1 for AgNPs(2)/ZHL, which is comparable to that of other AgNPs deposited on inorganic substrate for 4-NP reduction. 16,24,25 The rate of the catalytic reaction was higher in the case of AgNPs(2)/ZHL, which can be associated to the higher amount of AgNPs (Table 1). As observed by Naik et al, 26 the rate of catalytic reaction is affected by the concentration or loading level of the catalytically active site (here in this work due to the presence of AgNPs).…”
Section: Application Of Agnps(x)/zhl Hybrids As Catalysts For Reductimentioning
confidence: 98%
“…The rate constant (k) calculated from the slope of the plot was 0.394 min -1 for AgNPs(1)/ZHL and 0.875 min -1 for AgNPs(2)/ZHL, which is comparable to that of other AgNPs deposited on inorganic substrate for 4-NP reduction. 16,24,25 The rate of the catalytic reaction was higher in the case of AgNPs(2)/ZHL, which can be associated to the higher amount of AgNPs (Table 1). As observed by Naik et al, 26 the rate of catalytic reaction is affected by the concentration or loading level of the catalytically active site (here in this work due to the presence of AgNPs).…”
Section: Application Of Agnps(x)/zhl Hybrids As Catalysts For Reductimentioning
confidence: 98%
“…Nenhuma redução catalítica foi observada na presença apenas do suporte δ-FeOOH puro, indicando que a atividade catalítica pode ser atribuída exclusivamente as nanopartículas de ouro. 3,20,24,25 Portanto, o uso do δ-FeOOH como suporte para a deposição de nanopartículas de ouro abre novas perspectivas para o emprego destes materiais como precursores para a produção de híbridos multifuncionais baseados em óxidos de ferro (III) decorados com nanopartículas metálicas através do tratamento térmico dos catalisadores AuNPs/FeOOH. 17,26 A cinética da reação pode ser facilmente obtida através dos espectros de absorção UV-vis dependentes do tempo (Figura 6).…”
Section: Redução Catalítica Do 4-nitrofenol Pelos Híbridos Aunps/feoohunclassified
“…21 foi também usada para a preparação de compostos híbridos contendo quitosona e nanopartículas de prata (AgNPs), como demostrado por Wang e colaboradores. 24 As AgNPs mostraram atividade catalítica para a hidrogenação do 4-NP a 4-AP na presença de NaBH 4 , na qual, de acordo com estes autores, a redução total do 4-NP aconteceu em aproximadamente 3 min de reação. Walker e Zaleski 25 também demostraram a preparação de híbridos multifuncionais feitos de Fe 3 O 4 @SiO 2 -M, em que M se refere às nanopartículas de ouro, prata e paládio para a redução catalítica de 4-nitrofenol.…”
Section: Introductionunclassified
“…Moreover, a novel core–shell-structured Ag-based magnetic functional polymer nanocatalyst, Fe 3 O 4 @SN/GLA@chitosan–Ag (SN = amino-functionalized SiO 2 , and GLA = glutaraldehyde), was fabricated by utilizing the stabilization function and reducing ability of renewable chitosan macromolecules in situ . 9 This system exhibited superior catalytic performance and long-term stability in the reduction of 4-NP. The reduction of organic dyes in the presence of the magnetic Fe 3 O 4 /Cu nanocomposite was also evaluated.…”
Section: Introductionmentioning
confidence: 98%