In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases

Peng, Song; Ouyang, Xiaoming; Wang, Yihan; Teng, Qing‐Hu; Li, Yan; Zhang, Xiuqing; Hu, Zhao‐Bo; Wang, Kai; Liang, Fu‐Pei

doi:10.1016/j.cclet.2022.108044

Cited by 2 publications

(2 citation statements)

References 41 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[21][22][23][24][25] Chiral lanthanide clusters will provide a platform for molecularbased materials with coordination between chirality and magnetism and exhibit great application prospects in the elds of three-dimensional displays, spintronic devices and magneto-optical memories. [26][27][28][29][30] Recently, Liang's group have in situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases. [27] Zou and coworker have designed and synthesized pinwheel/twist-shaped chiral lanthanide clusters with rotor structures by an annular/linear growth mechanism.…”

Section: Introductionmentioning

confidence: 99%

“…[26][27][28][29][30] Recently, Liang's group have in situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases. [27] Zou and coworker have designed and synthesized pinwheel/twist-shaped chiral lanthanide clusters with rotor structures by an annular/linear growth mechanism. [28] Besides, they constructed dysprosium clusters by regulating the hydroxyl coordination sites at different positions on the ligands [29] and carefully regulating the hydrolysis of lanthanide metal ions and the resulting hydrolysis products, which provides a method for the creation of chiral high-nucleation lanthanide clusters with unique forms.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

A homochiral hexagadolinium phosphonate cluster with a large magnetocaloric effect

Qian,

Huang,

Jia

et al. 2024

Preprint

View full text Add to dashboard Cite

A homochiral hexagadolinium phosphonate cluster designated as R/S-[Gd6(pmhpH)8(NO3)2(H2O)8]·19H2O (R/S-1) was successfully obtained and analyzed using single crystal X-ray diffraction crystallography, IR spectrum, TG analysis and magnetic testing. The cluster, shaped like a lantern, is constructed from {GdO8} polyhedra and {PO3C} tetrahedra surrounded by eight pmhpH2- ligands. Within the structure, two types of gadolinium ions with different coordination modes are observed. Each Gd(III) ion is bound to two carboxylate oxygens and six phosphonate oxygens from the coordinated pmhpH2- ligands. Circular dichroism spectra comfirmed that R/S-1 exists as a pair of enantiomers. Moreover, the cluster exhibits high thermal stability, decomposing at temperatures exceeding 335°C. Notably, the magnetic measurements revealed that compound R-1 exhibits a good magnetocaloric effect (MCE) with a maximum entropy change of − ΔSmmax =36.84 Jkg− 1 K− 1 at T = 2K and ΔH = 7 T.

show abstract

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

A homochiral hexagadolinium phosphonate cluster with a large magnetocaloric effect

Qian,

Huang,

Jia

et al. 2024

Preprint

View full text Add to dashboard Cite

show abstract

A Homochiral Hexagadolinium Phosphonate Cluster: Structure, Chiral Electrochemical Recognition and a Large Magnetocaloric Effect

Qian,

Huang,

Jia

et al. 2024

Eur J Inorg Chem

View full text Add to dashboard Cite

Chiral lanthanide clusters have promising applications in chiral recognition, magneto‐optical memories, and spintronic devices. Nonetheless, the precise prediction and controlled development of homochiral polynuclear Ln‐complexes is still a challenge. Herein, through multidentate chelate synthetic strategy, a new homochiral hexagadolinium phosphonate cluster designated as R/S‐[Gd6(pmhpH)8(NO3)2(H2O)8]·19H2O (R/S‐1) was successfully obtained by reacting chiral phosphonomethylhomoproline(pmhpH3) with Gd(III) salt. The cluster, shaped like a lantern, is constructed from {GdO8} polyhedra and {PO3C} tetrahedra surrounded by eight pmhpH2‐ ligands. Within the structure, two types of gadolinium ions with different coordination modes are observed. Each Gd(III) ion is bound to two carboxylate oxygens and six phosphonate oxygens from the coordinated pmhpH2‐ ligands. Circular dichroism spectra comfirmed that R/S‐1 exists as a pair of enantiomers. Moreover, the cluster exhibits high thermal stability, decomposing at temperatures exceeding 335 °C. Notably, the chiral cluster materials can be used for enantiomeric recognition for tryptophan (Trp) with the differential pulse voltammetry (DPV) peak current ratio (ID/IL) 2.74. Besides, the magnetic measurements revealed that compound R‐1 exhibits a good magnetocaloric effect (MCE) with a maximum entropy change of −ΔSmmax =36.84 Jkg−1 K−1 at T = 2K and ΔH = 7 T.

show abstract

In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases

Cited by 2 publications

References 41 publications

A homochiral hexagadolinium phosphonate cluster with a large magnetocaloric effect

A homochiral hexagadolinium phosphonate cluster with a large magnetocaloric effect

A Homochiral Hexagadolinium Phosphonate Cluster: Structure, Chiral Electrochemical Recognition and a Large Magnetocaloric Effect

Contact Info

Product

Resources

About