In vitro monitoring of glutathione via a switched-on effect based on a lanthanide incorporated carbon nanostructure with biocompatibility

Qin, Wen; Zeng, Zhi; Liu, Wanqiang; Gao, Jinwei; Zhang, Helen Meihua; Zhang, Cheng Cheng; Zheng, Yufeng

doi:10.1016/j.synthmet.2019.116183

Cited by 5 publications

(2 citation statements)

References 43 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In this context, owing to its large Stokes shift, narrow emission wavelength, and long luminescence lifetime, europium (Eu 3+ ) has attracted particular interest in luminescence applications [ 13 – 15 ]. Eu 3+ presents high K-edge values and X-ray coefficients because Eu has a high atomic number, and so Eu 3+ efficiently absorbs X-rays for CT imaging [ 16 ].…”

Section: Introductionmentioning

confidence: 99%

Lanthanide-based metal–organic frameworks solidified by gelatin-methacryloyl hydrogels for improving the accuracy of localization and excision of small pulmonary nodules

Wang

Gong

et al. 2022

J Nanobiotechnol

View full text Add to dashboard Cite

The localization of invisible and impalpable small pulmonary nodules has become an important concern during surgery, since current widely used techniques for localization have a number of limitations, such as invasive features of hookwires and microcoils, and rapid diffusion after injection of indocyanine green (ICG). Lanthanide-based metal–organic frameworks (MOFs) have been proven as potential fluorescent agents because of their prominent luminescent characteristics, including large Stokes shifts, high quantum yields, long decay lifetimes, and undisturbed emissive energies. In addition, lanthanides, such as Eu, can efficiently absorb X-rays for CT imaging. In this study, we synthesized Eu-UiO-67-bpy (UiO = University of Oslo, bpy = 2,2'-bipyridyl) as a fluorescent dye with a gelatin-methacryloyl (GelMA) hydrogel as a liquid carrier. The prepared complex exhibits constant fluorescence emission owing to the luminescent characteristics of Eu and the stable structure of UiO-67-bpy with restricted fluorescence diffusion attributed to the photocured GelMA. Furthermore, the hydrogel provides stiffness to make the injection site tactile and improve the accuracy of localization and excision. Finally, our complex enables fluorescence-CT dual-modal imaging of the localization site.

show abstract

Section: Introductionmentioning

confidence: 99%

Lanthanide-based metal–organic frameworks solidified by gelatin-methacryloyl hydrogels for improving the accuracy of localization and excision of small pulmonary nodules

Wang

Gong

et al. 2022

J Nanobiotechnol

View full text Add to dashboard Cite

show abstract

“…In this context, owing to its large Stokes shift, narrow emission wavelength, and long luminescence lifetime, europium (Eu 3+ ) has attracted particular interest in luminescence applications [13][14][15]. Eu 3+ presents high K-edge values and X-ray coe cients because Eu has a high atomic number, and so Eu 3+ e ciently absorbs X-rays for CT imaging [16].…”

Section: Introductionmentioning

confidence: 99%

Lanthanide-Based Metal–Organic Frameworks Solidified by Gelatin-Methacryloyl Hydrogels For Improving the Accuracy of Localization and Excision of Small Pulmonary Nodules

Wang

et al. 2021

Preprint

View full text Add to dashboard Cite

The localization of invisible and impalpable small pulmonary nodules has become an important concern during surgery, since current widely used techniques for localization, such as hookwires, microcoils, and indocyanine green (ICG), have a number of limitations. For example, hookwires and microcoils may cause complications because of their invasive features, while ICG undergoes rapid diffusion after injection and has limited application in the localization of deep-seated lesions. In contrast, lanthanide-based metal–organic frameworks (MOFs) have been proven as potential fluorescent agents because of their prominent luminescent characteristics, including large Stokes shifts, high quantum yields, long decay lifetimes, and undisturbed emissive energies. In addition, lanthanides, such as Eu, can efficiently absorb X-rays for CT imaging. In this study, we synthesized Eu-UiO-67-bpy (UiO = University of Oslo, bpy = 2,2'-bipyridyl) as a fluorescent dye with a gelatin-methacryloyl (GelMA) hydrogel as a liquid carrier. The prepared complex exhibits constant fluorescence emission owing to the luminescent characteristics of Eu and the stable structure of UiO-67-bpy with restricted fluorescence diffusion attributed to the photocured GelMA. Furthermore, the hydrogel provides stiffness to make the injection site tactile and improve the accuracy of localization and excision. Finally, our complex enables fluorescence-CT dual-modal imaging of the localization site.

show abstract

Powering Hydrogen Evolution Reaction by Precise Control Over A Cu‐Ni Bimetallic Electrocatalyst

Liu,

Luo,

Liao

et al. 2024

Applied Organom Chemis

View full text Add to dashboard Cite

Precious metals are effective catalysts for the hydrogen evolution reaction, but their high cost with complicated operation steps drives people to search for non–noble‐metal alternatives. Building rational design concept for efficient electrocatalyst relies on the capability to control the structure and composition. Herein, a Ni/Cu bimetallic mesoporous MOFs with 4,4′,4″‐(1,3,5‐triazine‐2,4,6‐triyl)tribenzoic acid as the robust ligand has been assembled via a one‐step solvothermal method. Due to the extensive conjugate plane and high nitrogen content, the catalyst possesses large pore size of 17 nm and fast electron transfer rate, which favors hydrogen bubble overflow and exposes more active sites to solid–liquid interfaces. The bimetallic interaction between highly conductive Cu ions and Ni ions allows it to improve charge migration and realize excellent conductivity. The functionalized electrode requires an overpotential of 132 mV to achieve 10 mA current density with a small Tafel slope (87.7 mV·dec−1) and continuous electrolysis for 24 h.

show abstract

In vitro monitoring of glutathione via a switched-on effect based on a lanthanide incorporated carbon nanostructure with biocompatibility

Cited by 5 publications

References 43 publications

Lanthanide-based metal–organic frameworks solidified by gelatin-methacryloyl hydrogels for improving the accuracy of localization and excision of small pulmonary nodules

Lanthanide-based metal–organic frameworks solidified by gelatin-methacryloyl hydrogels for improving the accuracy of localization and excision of small pulmonary nodules

Lanthanide-Based Metal–Organic Frameworks Solidified by Gelatin-Methacryloyl Hydrogels For Improving the Accuracy of Localization and Excision of Small Pulmonary Nodules

Powering Hydrogen Evolution Reaction by Precise Control Over A Cu‐Ni Bimetallic Electrocatalyst

Contact Info

Product

Resources

About