2020
DOI: 10.1103/physrevb.101.180403
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Incipient multiferroicity in Pnma fluoroperovskite NaMnF3

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Cited by 15 publications
(10 citation statements)
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“…It is worth noting that the ferroelectric instability in fluoroperovskites originates from geometric ionic size effects without noticeable hybridization, which plays a crucial role in the oxide perovskites [20]. The latter prediction was experimentally corroborated and it has been observed that the bulk crystal of the orthorhombic fluoroperovskite NaMnF 3 , with the lowest tolerance factor t = 0.78, is an incipient multiferroic in which incipient ferroelectricity coexists and even interacts with antiferromagnetic ordering below the Néel temperature T N = 66 K [23]. Furthermore, it was shown that the strained thin film of NaMnF 3 is ferroelectric already at room temperature [24; 25].…”
Section: Introductionmentioning
confidence: 82%
“…It is worth noting that the ferroelectric instability in fluoroperovskites originates from geometric ionic size effects without noticeable hybridization, which plays a crucial role in the oxide perovskites [20]. The latter prediction was experimentally corroborated and it has been observed that the bulk crystal of the orthorhombic fluoroperovskite NaMnF 3 , with the lowest tolerance factor t = 0.78, is an incipient multiferroic in which incipient ferroelectricity coexists and even interacts with antiferromagnetic ordering below the Néel temperature T N = 66 K [23]. Furthermore, it was shown that the strained thin film of NaMnF 3 is ferroelectric already at room temperature [24; 25].…”
Section: Introductionmentioning
confidence: 82%
“…Fluoroperovskites have received a lot of interest recently due to its usage in a variety of industries, including semiconductor production, scintillation materials, radiation dosimeters and lenses in optical lithography [ 1 , 2 , 3 ]. Experimentally and computationally by a various authors have been intensively researched on Fluoroperovskites compounds [ 4 , 5 , 6 , 7 ] due to their vast range of application.…”
Section: Introductionmentioning
confidence: 99%
“…Despite the variety of currently known magnetoelectric materials, perovskite-like structures remain the most researched MFs compounds. The family of perovskites stands out for its diversity due to the intrinsic instability of the cubic parent perovskite phase [2]. Crystallographic distortions owing to the substitution of various cations at A and B positions can lead to the emergence of ferroelectric and MF properties due to the hybridization of ion orbitals, tilt of oxygen octahedra (BO 6 ), doping of various cations, and other factors [3].…”
Section: Introductionmentioning
confidence: 99%