Inclusion complexes naphthalene-γ-cyclodextrin-adamantane and naphthalene-γ-cyclodextrin-o-carborane: the structure and luminescence properties

Nazarov, V. B.; Avakyan, V. G.; Vershinnikova, T. G.; Алфимов, М. В.; Rudyak, Vladimir Yu.

doi:10.1007/s11172-012-0098-2

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Host–Guest Chemistry of Carboranes: Synthesis of Carboxylate Derivatives and Their Binding to Cyclodextrins

Nekvinda

Grüner

Gabel

et al. 2018

Chemistry A European J

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Polyhedral carboxymethyl carborane (C B H ) derivatives, including mono- and disubstituted o-, m-, and p-isomers, have been synthesized. Supramolecular host-guest complexation of these derivatives with cyclodextrins (CDs; namely, α-, β-, and γ-CD) has been investigated in water. The globular structure of the carborane binding moiety and its hydrophobic character qualify it as an ideal recognition site to form stable inclusion complexes with macrocyclic host molecules in aqueous solution. The measured binding affinities for the carborane derivatives were in the millimolar range (K =10 -10 m ) with differently sized CDs, and preferential binding to β-CD.

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