Incorporation of dendritic silica nanoparticles for the preparation of high‐performance thin‐film nanocomposite membranes

Abstract

The development of thin‐film nanocomposite (TFN) membranes with high performance is conducive to efficient desalination and wastewater treatment. In this work, dendritic mesoporous silica nanoparticles (DLSiO2) were synthesized by a dual‐templating strategy. Afterward, they were introduced into the aqueous phase to fabricate TFN membranes via in situ interfacial polymerization (IP) reaction. Powerful techniques as scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, Nano zetasizer‐DLS, x‐ray photoelectron microscopy, electrokinetic analyzer, and contact angle were used in the characterization of dendritic structures and nanocomposite membranes. Results revealed that DLSiO2 with special structural characteristics can effectively regulate the IP process, promoting the enhancement of the crosslinking degree, surface hydrophilicity, and surface negative charge of polyaimde (PA) selective layers. It is also beneficial for constructing extra water channels within the PA selective layer to boost the transport of water molecules. As a consequence, the prepared TFN membrane with 0.3 mg/mL DLSiO2 exhibits optimal separation performance and good pressure resistance, acid–base resistance, and anti‐fouling properties. It also exhibited a water permeability of 4.17 L m−2 h−1 bar−1 (increased by 61.7% compared with thin film composites (TFC) membrane) and a NaCl rejection of 99.0%, which were better than those of TFN membranes prepared by introducing other types of silica in other studies.