Abstract. Stratospheric ozone transported to the troposphere is
estimated to account for 5 %–15 % of the tropospheric ozone sources.
However, the chances of intruded stratospheric ozone reaching the surface are
low. Here, we report an event of a strong surface ozone surge of
stratospheric origin in the North China Plain (NCP, 34–40∘ N,
114–121∘ E) during the night of 31 July 2021. The hourly
measurements reveal surface ozone concentrations of up to 80–90 ppbv at several
cities over the NCP from 23:00 LST (Local Standard time, = UTC +8 h) on 31
July to 06:00 LST on 1 August 2021. The ozone enhancement was 40–50 ppbv
higher than the corresponding monthly mean. A high-frequency surface
measurement indicates that this ozone surge occurred abruptly, with an
increase reaching 40–50 ppbv within 10 min. A concurrent decline in
surface carbon monoxide (CO) concentrations suggests that this surface ozone
surge might have resulted from the downward transport of a stratospheric ozone-rich and
CO-poor air mass. This is further confirmed by the vertical evolutions of
humidity and ozone profiles based on radiosonde and satellite data
respectively. Such an event of stratospheric impact on surface ozone is
rarely documented in view of its magnitude, coverage, and duration. We find that this surface ozone surge was induced by a combined effect of
dying Typhoon In-fa and shallow local mesoscale convective systems (MCSs)
that facilitated transport of stratospheric ozone to the surface. This
finding is based on analysis of meteorological reanalysis and radiosonde
data, combined with high-resolution Weather Research and Forecasting (WRF)
simulation and backward trajectory analysis using the FLEXible
PARTicle (FLEXPART) particle dispersion model. Although Typhoon In-fa on the
synoptic scale was at its dissipation stage when it passed through the NCP,
it could still bring down a stratospheric dry and ozone-rich air mass. As a
result, the stratospheric air mass descended to the middle-to-low troposphere
over the NCP before the MCSs formed. With the pre-existing stratospheric
air mass, the convective downdrafts of the MCSs facilitated the final descent
of stratospheric air mass to the surface. Significant surface ozone
enhancement occurred in the convective downdraft regions during the
development and propagation of the MCSs. This study underscores the
substantial roles of weak convection in transporting stratospheric ozone to
the lower troposphere and even to the surface, which has important implications
for air quality and climate change.