BACKGROUND: Biogas (GB) and methane (BMP) potentials are important parameters to know the energy potential in the anaerobic digestion of municipal solid wastes (MSW) and to design full-scale facilities. However, no standard protocol is defined for this measure.RESULTS: Several samples of mixed municipal solid waste (MSW) and the source-selected organic fraction of municipal solid waste (OFMSW) obtained at different stages of their mechanical-biological treatment were analyzed. GB and BMP values obtained at different times were correlated. Biogas potentials calculated at 3, 4, 5, 6, 7, 14, 21, 50 and 100 days correlated well for the OFMSW samples. In the case of the MSW samples, only GB values obtained at times of 14 or more days correlated well with the ultimate biogas production (considered at 100 days). The biogas potential analyzed at 21 days proposed in some standard methods accounted for the 77% of total biogas potential in the OFMSW samples and for the 71% in the MSW samples, respectively.
CONCLUSIONS:The results are useful for the correct design and operation of anaerobic digestion plants in terms of retention time estimation and to know the expected biogas and methane productions.Keywords: Anaerobic digestion; Biogas; Waste treatment and waste minimization; Characterisation, Process optimisation, Residues.P r e -p r i n t Several studies related to the production of biogas and methane from different organic wastes have been published. In the field of MSW, the main objective of the published works is to determine the potential amount of biogas or methane that can be obtained from anaerobic digestion. 4 Source-separated collection systems for the organic fraction of MSW have been implemented in different European states.For this reason, the determination of the biogas and methane potentials of these wastes is of special interest. In other published studies, the main objective is to determine the optimal conditions of the biogas production tests. [5][6][7] Typically, the duration of these anaerobic tests is often long, which limits their application at industrial scale.The objective of this research is to study in detail the biogas and methane productions of several samples of MSW from different origins and to obtain a general correlation between biogas and methane productions vs. time. This correlation can be useful for a rapid knowledge of MSW energy potential.
MATERIALS AND METHODS
Waste samplesSamples were obtained from different sources to include all the possible range of biogas and methane potentials. Table 1 shows the codification and treatment that correspond to each sample. Fresh (untreated) samples, such as the OFMSW and mixed MSW, were directly obtained from collection trucks. Three P r e -p r i n t 2 samples of each fraction were collected from six different municipalities near the city of Barcelona.Treated samples were obtained from a mechanical-biological waste treatment plant located in Barcelona (Spain) with a total capacity of 240,000 Mg per year. 8 Briefly, the plant operation...