Indium oxide nanoparticles embedded in TUD-1 as a highly selective catalyst for toluene to benzaldehyde oxidation using TBHP as oxidant

Das, Prangya Paramita; Chowdhury, Biswajit

doi:10.1007/s11696-020-01054-z

Cited by 5 publications

(3 citation statements)

References 32 publications

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“…More recently, a wide variety of metal and metal oxide nanoparticles have been used for the selective oxidation of toluene via C-H activation, and examples of the selective formation of benzaldehyde are listed in Scheme 5 [65][66][67][68][69].…”

Section: Toluene C(sp3)-h Activationmentioning

confidence: 99%

“…More recently, a wide variety of metal and metal oxide nanoparticles have bee for the selective oxidation of toluene via C-H activation, and examples of the se formation of benzaldehyde are listed in Scheme 5 [65][66][67][68][69]. In 2013, Rao and coworkers [65] reported the C-H bond activation of toluene ing metal peroxide nanoparticles, CdO2 and ZnO2, prepared by a reaction of the sponding oxide with H2O2.…”

Section: Toluene C(sp3)-h Activationmentioning

confidence: 99%

“…In 2020, Das and Chowdhury [66] described the use of indium oxide nanoparticles embedded in mesoporous silica TUD-1 (In-TUD-1) for the green synthesis of benzaldehyde from toluene using TBHP as oxygen donor and acetic acid as solvent, under very mild reaction conditions (80 • C, 5 h). The catalyst showed high catalytic activity with 48% toluene conversion and 83% benzaldehyde selectivity.…”

Section: Toluene C(sp3)-h Activationmentioning

confidence: 99%

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Metal and Metal Oxide Nanoparticles Catalyzed C–H Activation for C–O and C–X (X = Halogen, B, P, S, Se) Bond Formation

2022

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The direct functionalization of an inactivated C–H bond has become an attractive approach to evolve toward step-economy, atom-efficient and environmentally sustainable processes. In this regard, the design and preparation of highly active metal nanoparticles as efficient catalysts for C–H bond activation under mild reaction conditions still continue to be investigated. This review focuses on the functionalization of un-activated C(sp3)–H, C(sp2)–H and C(sp)–H bonds exploiting metal and metal oxide nanoparticles C–H activation for C–O and C–X (X = Halogen, B, P, S, Se) bond formation, resulting in more sustainable access to industrial production.

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Section: Toluene C(sp3)-h Activationmentioning

confidence: 99%