To improve the operation performance and energy conversion efficiency of the redox flow battery (RFB), a modular active balancing circuit for redox flow battery applied in the energy storage system is proposed in this paper. Detailed topology description, parameter design, characteristic analysis, operation principle and control strategy of the proposed circuit are presented and discussed in the paper. Different from the conventional battery balancing circuit, the key point of the proposed balancing circuit is that it integrates the circulating pump driving circuit and the state-of-charge (SOC) equalization circuit of the redox flow battery. It uses the energy consumption of the pump driving to balance the SOCs of different battery stacks, which provides a new SOC balancing mechanism for RFB. Based on the proposed circuit, an active balancing control strategy using the time-sharing energy transmission method is proposed, in which the sub-modules of the circuit are alternatively configured in charge-state and discharge-state for absorbing energy or releasing energy to achieve the SOC balancing control for RFB. Compared with the conventional balancing solution or circuit, the proposed modular active balancing circuit simplifies the complexity of the battery management system for RFB, which has the advantages of high efficiency, high reliability, and good scalability. Simulations on Matlab/Simulink and experiments on a downscaled prototype were carried out to verify the feasibility and effectiveness of the proposed circuit and control strategy.INDEX TERMS Redox flow battery (RFB), active balancing circuit, battery management system (BMS), state-of-charge (SOC) balance, capacitive energy transfer.