Industrial Investigation of the Combined Action of Vacuum Residue Hydrocracking and Vacuum Gas Oil Catalytic Cracking While Processing Different Feeds and Operating under Distinct Conditions

Abstract

Ebullated bed vacuum residue hydrocracking and fluid catalytic cracking (FCC) are among the most profitable processes in modern refining. Their optimal performance is vital for petroleum refining profitability. That is why a better understanding of their combined action and the interrelations between these two heavy oil conversion processes in a real-world refinery could provide valuable information for further performance optimization. Nine distinct petroleum crudes belonging to the extra light, light, and medium petroleum crude types were processed in the LUKOIL Neftohim Burgas refinery to study the combined performance of two processes: FCC of vacuum gas oil and ebullated bed vacuum residue H-Oil hydrocracking. The operating conditions along with the characterization data of the feeds and products of both processes were evaluated through the employment of intercriteria analysis to define the variables with statistically significant relationships. Maple 2023 Academic Edition mathematics software was used to develop models to predict the vacuum residue conversion level under different operating conditions. The plug flow reactor model with an activation energy of 215 kJ/mol and a reaction order of 1.59 was found to provide the highest accuracy of vacuum residue conversion, with an average absolute deviation of 2.2%. H-Oil yields were found to correlate with the vacuum residue conversion level and the content of FCC slurry oil (SLO), the recycling of partially blended fuel oil, a material boiling point below 360 °C, and the vacuum gas oil (VGO) in the H-Oil feed. FCC conversion was found to depend on the H-Oil VGO content in the FCC feed and the content of FCC SLO in the H-Oil feed.

Alternative Options for Ebullated Bed Vacuum Residue Hydrocracker Naphtha Utilization

“…The processing of H-Oil naphtha during the study was carried out at the LNB FCCU and Prime G FCC gasoline hydrotreatment. A process scheme of the LNB FCC unit is presented in [38]. The catalysts used in the FCC unit during the study were octane barrel main catalyst and ZSM-5 containing catalyst additive, whose properties are summarized in Table 2.…”