Industrial Synthetic Method of the Rubbers

Sone, T.

doi:10.2324/gomu.88.178

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Cited by 5 publications

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Polybutadiene Rubber

Mohanty

Gupta

2023

Kirk-Othmer Encyclopedia of Chemical Technology

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Polybutadiene (PBR) occupies the second position among synthetic rubber after styrene‐butadiene rubber with a global production capacity of ∼2.8 million metric tons per year. It is produced by solution polymerization process using the Ziegler‐Natta catalyst system. PBR with varied microstructure feature is produced using different types of transition metal in combination with alkyl aluminum. The presence of different microstructures in the product impact properties and performances of the rubber. This article focuses on PBR polymerization processes with different types of catalyst systems and their effect on microstructure of products.

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Polybutadiene Rubber

Mohanty

Gupta

2023

Kirk-Othmer Encyclopedia of Chemical Technology

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Kuhn–Mark–Houwink–Sakurada Coefficients for Determination of Molecular Parameters of cis-Polybutadiene Rubbers by Gel Permeation Chromatography

Makhiyanov

Davletbaev

2018

Polym. Sci. Ser. A

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Long-Branched Structure of Polybutadienes Analyzed by Rheology

Maeda

Shiba

Suzuki

2021

J. Soc. Rheol., Jpn

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forlong-branchedPBsincreaseswithPBconcentration,andalsoincreasesfor morecomplexlong-branchedstructures.ThevaluesofG′c −2 forY2andVwerenotdependentonconcentration.There-sultsshowedthatY2andVhavelinearmolecularstructuresandthatY1,Co1,andCo2havelong-branchedstructures, withtheorderofcomplexitybeingY1>Co1>Co2.Fromthedampingfunctionsevaluatedbylarge-deformationstressrelaxation measurements of the 30% PB solutions, the order of long-branched structural complexity was Y1>Co1>Co2>V≈Y2.ThisorderwasessentiallythesameasthatbasedonthelinearviscoelasticityofthePBsamples.Therheologicalmethodinthisstudyprovidesstructuralinformationaboutlong-branchedPBs.

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Industrial Synthetic Method of the Rubbers

Cited by 5 publications

References 9 publications

Polybutadiene Rubber

Polybutadiene Rubber

Kuhn–Mark–Houwink–Sakurada Coefficients for Determination of Molecular Parameters of cis-Polybutadiene Rubbers by Gel Permeation Chromatography

Long-Branched Structure of Polybutadienes Analyzed by Rheology

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