“…The H x VO x+y species having V‐O bond is covalent character and V‐O‐V does not show acidic character only terminal hydroxyl groups show acidity, Mo‐O bond is more stabilized by the strong overlap of O 2p and Mo d orbitals, hence both H x VO x+y and H x MoO x+y showed less acidity. And H x WO x+y more acidic nature by the delocalization of electrons lead to bridging hydrogen, terminal hydroxyl groups and with high electronegativity ,. Further, the acid sites strength of V and Mo are almost similar to gA, while W showed two distinguishable peaks, one at lower temperature range between 90‐220 °C and another at 300‐430 °C.…”