Natural fiber-reinforced polymer composite is a rapidly growing topic of research due to the simplicity of obtaining composites that is biodegradable and environmentally friendly. The resulting composites have mechanical properties comparable to synthetic fiber-reinforced composites. In this regard, the present work is formulated with the objectives related to the development, characterization, and optimization of the wt% of reinforcements and the process parameters. The novelty of this work is related to the identification and standardization of the appropriate wt% of reinforcements and parameters for the processing of the areca nut leaf sheath fiber-based polymer composites for enhanced performance attributes. With this basic purview and scope, the composites are synthesized using the hand layup process, and the composite samples of various fiber compositions (20%, 30%, 40%, and 50%) are fabricated. The mechanical characteristics of biodegradable polymer composites reinforced with areca nut leaf sheath fibers are investigated in the present work, with a focus on the effect of fiber composition (tensile properties, flexural strength, and impact strength). The properties of composites are enhanced by combining the areca nut leaf sheath fiber and epoxy resin, with a fiber content of 50% being the optimal wt%. The Scanning electron microscopy (SEM) investigations also ascertain this by depicting the good interfacial adhesion between the areca nut leaf sheath fiber and the epoxy resin. The tensile strength of the composite specimen reinforced with 50% areca nut fiber increases to 44.6 MPa, while the young’s modulus increases to 1900 MPa, flexural strength increases to 64.8 MPa, the flexural modulus increases to 37.9 GPa, and impact strength increases to 34.1 k J/m2. As a result, the combination of areca nut leaf sheath fiber reinforced epoxy resin shows considerable potential as a renewable and biodegradable polymer composite. Furthermore, areca nut leaf sheath fiber-reinforced epoxy resin composites are likely to replace petroleum-based polymers in the future. The ecosustainability and biodegradability of the composite specimen alongside the improved mechanical characteristics serve as the major highlight of the present work, and can help the polymer composite industry to further augment the synthetic matrix and fiber-based composites with the natural fiber-reinforced composites.