In order to solve the complicated process and low efficiency and low accuracy of solving a class of matrix equations, this paper introduces the linear saturated system model neural network architecture to solve the bisymmetric solution of a class of matrix equations. Firstly, a class of matrix equations is constructed to determine the key problems of solving the equations. Secondly, the linear saturated system model neural network structure is constructed to determine the characteristic parameters in the process of bisymmetric solution. Then, the matrix equations is solved by using backpropagation neural network topology. Finally, the class normalization is realized by using the objective function of bisymmetric solution, and the bisymmetric solution of a class of matrix equations is realized. In order to verify the solving effect of the method in this paper, three indexes (accuracy, correction accuracy, and solving time) are designed in the experiment. The experimental results show that the proposed method can effectively reduce the solving time, can improve the accuracy and correction effect of the bisymmetric solution, and has high practicability.