Understanding potentiometry is a difficult task when
students in
initial courses of Analytical Chemistry are first introduced to instrumental
techniques. The closest instrument to them is a pH meter, which is
frequently used as a “black box”, without a real understanding
of how it works. Here we present the assembly of jelly modules that
the students can combine in different ways with the purpose of visualizing
what reference and indicator electrodes are and their function when
they are used in potentiometric measurements with quantitative purposes.
This didactic sequence was used during six semesters in a first course
of Analytical Chemistry dictated for students becoming laboratory
technicians in Chemistry and Chemical Engineering. It is a hands-on
experiment to exemplify both a direct potentiometric analysis and
a potentiometric titration (indirect analysis). It is simple, low-cost,
and easy to apply. It only requires gelatin, salts, pieces of metal,
and a multimeter. The students showed interest in its execution, and
they were able to identify the functions of the electrodes, discuss
the different analytical implications of potentiometric techniques
among themselves, and make the requested graphics with very good results.