The level and distribution of physiochemical contaminants (cadmium, chromium, copper, iron, nickel, lead, zinc, temperature, pH, suspended solids (SS), dissolved solids (DS), conductivity, oil and grease, dissolved oxygen (DO), biochemical oxygen demand (BOD), chemical oxygen demand (COD) and phenol) were investigated in water samples obtained from River Ijana and the Warri Refinery and Petrochemical Company (WRPC) effluents, using APHA standard methods of wastewater analysis. This research is aimed at quantifying the contribution of the refinery effluent, ruralyurban runoff, refinery sludge lagoon to the pollution load of the river, and the magnitude of trace metal flux to Tobi creek. for BOD, 40.88 and 52.64 mg L À 1 for COD and 0.97 and 1.37 mg L À 1 for phenol. Correlation analysis shows that P50.05, and is significant for conductivity, SS, DS, oil and grease, BOD, COD, Cd, Cu, Fe, Ni, Pb and Zn. When compared with WHO/FEPA permissible limits for aquatic ecosystems, our results are indicative of the contribution of pollutant from the refinery effluent. The refinery sludge lagoon is also suspected to be responsible for the elevated concentrations downstream of the river.