“…To achieve the maximum light harvesting and surface reactions, numerous strategies have been adopted, such as heteroatomic doping, heterostructure formation, , and modification of the thickness of g-C 3 N 4 nanosheets . Among these, heterostructure formation plays a vital role in advancing the field of photocatalysis. − Heterostructures showed effective electron–hole pair separation, prolonged light absorption, and synergistic effects that boost the catalytic activity of the materials. − In this regard, we have fabricated a Z-scheme MoS 2 /g-C 3 N 4 heterostructure that aids in suppressing the natural back reaction (e–h+ pair recombination), enhances the conductivity, and increases the catalytically active sites of g-C 3 N 4 for HER. , Therefore, MoS 2 /g-C 3 N 4 heterostructured catalytic systems can accelerate the HER efficiency through Z-scheme band alignment of their band structures, which eases out the transfer of electrons through interface electron channels . The interfacial layered engineering is feasible in a MoS 2 /g-C 3 N 4 system owing to the analogous layered structure that subdues the lattice mismatch between them by forming a homogeneous 2D/2D nanohybrid through the planar growth of MoS 2 layers over g-C 3 N 4 , Therefore, with the aim of exploiting synergistic effects between these two semiconductors, herein, we have fabricated MoS 2 /g-C 3 N 4 heterostructured catalysts for determining their excellence toward PC, EC, and PEC water splitting.…”