Influence of catalyst additives on vapor-phase hydrogenation of furfural to furfuryl alcohol on impregnated copper/magnesia

Shirvani, Samira; Ghashghaee, Mohammad; Farzaneh, Vahid; Sadjadi, Samahe

doi:10.1007/s13399-017-0244-z

Cited by 22 publications

(14 citation statements)

References 30 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Furthermore, synergistic interactions between two metals may also play a crucial role in the interaction of substrate and different reaction intermediates with the catalyst surface. In this direction, bimetallic Cu catalysts have shown higher activity for the hydrogenation of carbonyl group of furan derivatives . Recently, Shirvani et al.…”

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass‐dermentioning

confidence: 99%

“…Recently, Shirvani et al. reported furfural hydrogenation over Co, Cr and Ca modified Cu/MgO . Among all the explored catalysts, Co additives have significantly influenced on the catalytic hydrogenation of furfural to furfuryl alcohol.…”

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass‐dermentioning

confidence: 99%

“…did not explain the observed high selectivity of furfuryl alcohol, as the formation of the hot spot under microwave irradiation could also lead to loss the selectivity for furfuryl alcohol. Similarly, Cu‐MgO catalyst resulted in an efficient hydrogenation of furfural to furfuryl alcohol, where the study inferred that Cu 0 /Cu + sites present on the surface of catalyst might be responsible for the observed higher catalytic activity of Cu catalyst . Furthermore, hydrogenation of furfural over Cu/CeO 2 resulted in the higher catalytic activity to yield furfuryl alcohol and 2‐MF in comparison to the pure Cu and CeO 2 .…”

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass‐dermentioning

confidence: 99%

“…In this direction, bimetallic Cu catalysts have shown highera ctivity for the hydrogenation of carbonyl group of furan derivatives. [60][61][62][63][64][65] Recently,S hirvani etal. reported furfuralh ydrogenation over Co, Cr and Ca modified Cu/ MgO.…”

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass-dermentioning

confidence: 99%

“…reported furfuralh ydrogenation over Co, Cr and Ca modified Cu/ MgO. [60] Among all the explored catalysts, Co additives have significantly influenced on the catalytic hydrogenation of furfural to furfuryla lcohol. Study revealed that higherc atalytic activity achievedo ver CuÀCo/MgO was due to the smallestc rystallite size of CuO facilitated by the presence of Co and higher dispersion of CuO.…”

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass-dermentioning

confidence: 99%

See 4 more Smart Citations

Metal Catalysts for the Efficient Transformation of Biomass‐derived HMF and Furfural to Value Added Chemicals

2018

View full text Add to dashboard Cite

Catalytic transformation of biomass‐derived compounds to different platform chemicals and liquid fuel is a prominent way to reduce the global dependence on fossil resources. In past few decades, biomass‐derived furans such as 2‐furfuraldehyde (furfural) and 5‐hydroxymethyl‐2‐furfural (HMF) have received outstanding attention because of their wide applications in the production of various industrially important value‐added chemicals and fuel components. Various catalytic systems and methodologies have been extensively explored for the transformation of these furans to a wide range of products including open ring diketones, ketoacids, alcohols and long chain alkanes. This Review is aimed to provide an extensive overview of the recent developments of several high‐performing heterogeneous catalysts for the catalytic upgradation of the key biomass‐derived furans (furfural and HMF) to value‐added chemicals. Moreover, the role of these catalysts in the catalytic transformations including hydrogenation, decarbonylation, oxidation, hydrogenolysis and ring opening reactions, and the mechanistic pathways are also highlighted in this Review.

show abstract

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass‐dermentioning

confidence: 99%

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass‐dermentioning

confidence: 99%

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass‐dermentioning

confidence: 99%

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass-dermentioning

confidence: 99%

Section: Catalytic Hydrogenation And/or Hydrogenolysis Of Biomass-dermentioning

confidence: 99%

See 3 more Smart Citations

Metal Catalysts for the Efficient Transformation of Biomass‐derived HMF and Furfural to Value Added Chemicals

2018

View full text Add to dashboard Cite

show abstract

Heterogeneous Bimetallic Catalysts for Upgrading Biomass‐Derived Furans

Singh

2018

Asian J Org Chem

View full text Add to dashboard Cite

Transformation of furans derived from biomass is a sustainable methodology to produce a wide range of chemicals for various applications. In this direction, involvement of catalysts and catalytic processes for biomass transformation is of critical importance to achieve enhanced transformation, controlled product selectivity and less‐energy intensive process. This review focuses on the recent progress in the field of catalytic transformation of biomass derived furfural and 5‐hydroxymethylfurfural (HMF) to various value‐added chemicals using bimetallic catalysts. This review provides a detailed overview on various factors controlling the performance of the bimetallic catalysts for various reactions (e. g., hydrogenation, oxidation, hydrodeoxygenation) involved during the transformation of these furans. In particular, importance of intermetallic synergistic interactions of the bimetallic heterogeneous catalysts in biomass transformation is highlighted.

show abstract

Ni@C@CNT catalyst derived from CNT doped Ni‐MOF for furfural hydrogenation to tetrahydrofurfuryl alcohol

Yuan

Liu

Guo

et al. 2022

Asia-Pacific J Chem Eng

View full text Add to dashboard Cite

Conversion of biomass-derived furfural platform compound to value-added tetrahydrofurfuryl alcohol (THFL) molecule is a sustainable route, and an efficient nonnoble metallic catalyst is a key factor for this reaction. In this work, Ni@C@CNT composite as a highly effective catalyst for hydrogenation of furfural to tetrahydrofurfuryl alcohol was synthesized by one-step pyrolysis of Nicentered metal organic framework (Ni-MOF) doping with carbon nanotube (CNT). For comparison, Ni@C catalyst derived directly from Ni-MOF was also synthesized. The characterization results show that the doping of CNT promotes high dispersion of active sites and formation of Ni 3 C phase which has Pt-like catalytic activity. Therefore, the obtained Ni@C@CNT exhibited excellent activity in furfural hydrogenation (99.1% furfural conversion and 94.7% THFL yield at 120 C, 4 h, 4-MPa initial hydrogen pressure). Ni@C@CNT also shows good stability in reuse test. Current work presents a facile method for preparation of nonnoble metallic catalysts with high efficiency.

show abstract

Influence of catalyst additives on vapor-phase hydrogenation of furfural to furfuryl alcohol on impregnated copper/magnesia

Cited by 22 publications

References 30 publications

Metal Catalysts for the Efficient Transformation of Biomass‐derived HMF and Furfural to Value Added Chemicals

Metal Catalysts for the Efficient Transformation of Biomass‐derived HMF and Furfural to Value Added Chemicals

Heterogeneous Bimetallic Catalysts for Upgrading Biomass‐Derived Furans

Ni@C@CNT catalyst derived from CNT doped Ni‐MOF for furfural hydrogenation to tetrahydrofurfuryl alcohol

Contact Info

Product

Resources

About